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Título: C[sbnd]S cross-coupling catalyzed by a series of easily accessible, well defined Ni(II) complexes of the type [(NHC)Ni(Cp)(Br)]
Autor: DAVID MORALES_MORALES
ID del Autor: info:eu-repo/dai/mx/orcid/0000-0002-7984-1819
Resumen: The synthesis, characterization and catalytic evaluation of a series of NHC-Ni(II) complexes1-Ni(-Me),2-Ni(-nBu) and3-Ni(-Bn) bearing a phthalimide fragment and a cyclopentadienyl (Cp) ligand is reported.The complexes were evaluated in CAS couplings of iodobenzene and a range of thiols. The reactions werecarried out using a catalyst loading of 5 mol % in DMF during 0.5–19 h. Being complex2-Nithe oneexhibiting the best activity for these transformations yielding up to 96% of products in 0.5 h
Fecha de publicación: 2020
Licencia: http://creativecommons.org/licenses/by-nc-nd/4.0
URI: http://rdu.iquimica.unam.mx/handle/20.500.12214/1228
metadata.dc.type.uri: https://doi.org/10.1016/j.jcat.2020.01.016
Lenguaje: eng
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